Thiacalixarenes (100)

Thiolorolines are macrocyclic compounds originating from calixarenes, with sulfur atoms substituting some of the oxygen atoms within the ring. These compounds serve as supramolecular host materials, capable of forming stable complexes with guest molecules through ion-dipole interactions and hydrogen bonding. The incorporation of sulfur atoms in the thiocalixarene ring introduces additional binding sites and enhances the regulation of host-guest interactions. Their applications span ion separation, catalysis, and the creation of advanced materials for sensing and molecular recognition. In the field of supramolecular chemistry, thiocalixarenes are employed to construct functional supramolecular assemblies and investigate innovative host-guest systems.